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Chemical Sensors: Simulation and Modeling Volume 5: Electrochemical Sensors by Ghenadii Korotcenkov

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CHAPTER 5

COMPUTER MODELING OF THE POTENTIOMETRIC RESPONSE OF ION-SELECTIVE ELECTRODES WITH IONOPHORE-BASED MEMBRANES

K. N. Mikhelson

1.  INTRODUCTION

Ion-selective electrodes (ISEs)—potentiometric sensors of ions—constitute the oldest and, probably, the most explored type of electrochemical sensors. Historically, progress in ISE theory and application relied on various tools. In the early years of ISE studies, very simple physical models were in use. Respectively, simple mathematics were adequate to quantify these models. Higher practical demands on the ISEs called for more advanced physical models, which, in turn, required more complicated mathematics. ...

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