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Electrochemically Enabled Sustainability
book

Electrochemically Enabled Sustainability

by Kwong-Yu Chan, Chi-Ying Vanessa Li
June 2014
Intermediate to advanced content levelIntermediate to advanced
519 pages
17h 58m
English
CRC Press
Content preview from Electrochemically Enabled Sustainability
196 Electrochemically Enabled Sustainability
octahedral sites, while lithium is displaced into adjacent tetrahedral sites
[10]. Such phase transformation incorporated with the Jahn–Teller distortion
effect reduces the structural stability of layered LiMnO
2
[11,12] and, hence,
limits its cycling performance. However, the spinel Li
x
Mn
2
O
4
(0 x 2) nano-
domain structure, in situ formed in the non-stoichiometric-layered LiMnO
2
is able to spontaneously switch between a cubic spinel and a tetragonal
spinel, as illustrated in Figure 5.5 [13]. Consequently, it leads to a dramatic
improvement in capacity retention from 61% after 10 cycles (no nano
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Publisher Resources

ISBN: 9781466575431