image (6.24)

It is also possible that N2O3 is produced. The kinetic reaction and equilibrium constant are given as:

NO+NO2N2O340kJ/mol

image

r=krRT(pNO·pNO2pN2O3Kp) (6.25)

image (6.25)

where (Thiemann et al., 1998):

Kp=PN2O3PNO·PNO2=65.3·109·exp(4740T) (6.26)

image (6.26)

Example 6.5

Plot the figure for the decomposition of N2O4 into NO2 as a function of ...

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