Book description
This work aims to familiarize students with the fundamentals of colloid and surface science, from various types of colloids and colloidal phenomena, and classical and modern characterization/measurement techniques to applications of colloids and surface science in engineering, technology, chemistry, physics and biological and medical sciences. The Journal of Textile Studies proclaims "High praise from peers . . .contains valuable information on many topics of interest to food rheologists and polymer scientists …[The book] should be in the libraries of academic and industrial food research organizations" and Chromatographia describes the book as "…an excellent textbook, excellently organised, clearly written and well laid out."
Table of contents
 Cover
 Half Title
 Title Page
 Copyright Page
 Table of Contents
 Preface to the Third Edition
 Acknowledgments
 Preface to the Second Edition
 Preface to the First Edition

1. Colloid and Surface Chemistry: Scope and Variables
 1.1 Introduction
 1.2 The Importance of the Surface for Small Particles
 1.3 Classification of Colloids Based on Affinity to Carrier Fluid
 1.4 Concept of Stability of Colloidal Systems
 1.5 Some Physical Characteristics of Colloids
 1.6 Some Classical and Emerging Experimental Tools
 1.7 An Overview of the Book
 Review Questions
 References
 Problems

2. Sedimentation and Diffusion and Their Equilibrium
 2.1 Introduction
 2.2 Sedimentation: Some Basic Considerations
 2.3 Gravitational Sedimentation
 2.4 Centrifugal Sedimentation
 2.5 Diffusion
 2.6 Brownian Motion and Diffusion
 2.7 The Random Coil and Random Walk Statistics
 2.8 Equilibrium Between Sedimentation and Diffusion
 Review Questions
 References
 Problems
 3. Solution Thermodynamics: Osmotic and Donnan Equilibria

4. The Rheology of Dispersions
 4.1 Introduction
 4.2 Newton’s Law of Viscosity
 4.3 ConcentricCylinder and ConeandPlate Viscometers
 4.4 The Poiseuille Equation and Capillary Viscometers
 4.5 The Equation of Motion: The NavierStokes Equation
 4.6 Einstein’s Theory of Viscosity of Dispersions
 4.7 Deviations from the Einstein Model
 4.8 NonNewtonian Behavior
 4.9 Viscosity of Polymer Solutions
 Review Questions
 References
 Problems

5. Static and Dynamic Light Scattering and Other Radiation Scattering
 5.1 Introduction
 5.2 Interaction of Radiation with Matter
 5.3 Scattering by Small Particles: Theory of Rayleigh Scattering
 5.4 Experimental Aspects of Light Scattering
 5.5 Extension to Larger Particles and to Intraparticle Interference Effects
 5.6 Interference Effects and Structure of Particles
 5.7 Scattering by Large, Absorbing Particles
 5.8 Dynamic Light Scattering
 Review Questions
 References
 Problems

6. Surface Tension and Contact Angle: Application to Pure Substances
 6.1 Introduction
 6.2 Surface Tension and Contact Angle: A First Look
 6.3 Thermodynamics of Surfaces: Surface Tension as Surface Free Energy
 6.4 Surface Tension: Implications for Curved Interfaces and Capillarity
 6.5 Effects of Curved Interfaces on Phase Equilibria and Nucleation: The Kelvin Equation
 6.6 Surface Tension and Contact Angle: Their Relation to Wetting and Spreading Phenomena
 6.7 Contact Angles: Some Complications
 6.8 Measuring Surface Tension and Contact Angle: Round Two
 6.9 Contact of Liquids with Porous Solids and Powders
 6.10 Molecular Interpretation of Surface Tension
 Review Questions
 References
 Problems

7. Adsorption from Solution and Monolayer Formation
 7.1 Introduction
 7.2 Insoluble Monolayers: Spreading of Surfactants on Aqueous Surfaces
 7.3 Experimental Measurement of Film Pressure
 7.4 Results of Film Balance Studies
 7.5 Viscous Behavior of TwoDimensional Phases
 7.6 Applications of Monolayers and Monolayer Concepts
 7.7 Adsorption from Solution: Thermodynamics
 7.8 The Gibbs Equation: Experimental Results
 7.9 Adsorption on Solid Surfaces
 7.10 Applications of Adsorption from Solution
 7.11 Adsorption in the Presence of an Applied Potential
 Review Questions
 References
 Problems

8. Colloidal Structures in Surfactant Solutions: Association Colloids
 8.1 Introduction
 8.2 Surfactants in Solution: Experimental Observations and Models
 8.3 Structure of Micelles
 8.4 Molecular Architecture of Surfactants, Packing Considerations, and Shapes of Micelles
 8.5 Critical Micelle Concentration and the Thermodynamics of Micellization
 8.6 Solubilization
 8.7 Catalysis by Micelles
 8.8 Reverse Micelles
 8.9 Emulsions and Microemulsions
 8.10 Some Applications of Microemulsions
 8.11 Biological Membranes
 Review Questions
 References
 Problems

9. Adsorption at Gas–Solid Interfaces
 9.1 Introduction
 9.2 Experimental and Theoretical Treatments of Adsorption: An Overview
 9.3 Thermodynamics of Adsorption: Phenomenological Perspective
 9.4 Thermodynamics of Adsorption: A Statistical Perspective
 9.5 Multilayer Adsorption: The BrunauerEmmettTeller Equation
 9.6 Energetics of Adsorption
 9.7 Adsorption in Porous Solids
 9.8 Adsorption on Crystal Surfaces
 9.9 Metal Surfaces and Heterogeneous Catalysis
 Review Questions
 References
 Problems

10. van der Waals Forces
 10.1 Introduction
 10.2 van der Waals Forces and Their Importance in Colloid and Surface Chemistry
 10.3 Molecular Interactions and Power Laws
 10.4 Molecular Origins and the Macroscopic Implications of van der Waals Forces
 10.5 van der Waals Forces Between Large Particles and Over Large Distances
 10.6 Calculating van der Waals Forces Between Macroscopic Bodies
 10.7 Theories of van der Waals Forces Based on Bulk Properties
 10.8 Effect of the Medium on the van der Waals Attraction
 Review Questions
 References
 Problems

11. The Electrical Double Layer and DoubleLayer Interactions
 11.1 Introduction
 11.2 Surface Charges and Electrical Double Layer: Background
 11.3 The Capacitor Model of the Double Layer
 11.4 The Diffuse Double Layer: The DebyeHuckel Approximation
 11.5 The DebyeHückel Approximation: Results
 11.6 The Electrical Double Layer: GouyChapman Theory
 11.7 Overlapping Double Layers and Interparticle Repulsion
 11.8 “NotQuiteIndifferent” Electrolytes: Stern Adsorption
 Review Questions
 References
 Problems

12. Electrophoresis and Other Electrokinetic Phenomena
 12.1 Introduction
 12.2 Mobilities of Small Ions and Macroions in Electric Fields: A Comparison
 12.3 Zeta Potential: Thick Electrical Double Layers
 12.4 Zeta Potential: Thin Electrical Double Layers
 12.5 Zeta Potential: General Theory for Spherical Particles
 12.6 Electroosmosis
 12.7 Streaming Potential
 12.8 The Surface of Shear and Viscoelectric Effect
 12.9 Experimental Aspects of Electrophoresis
 12.10 Determining the Surface Charge from Electrokinetic Measurements
 12.11 Applications of Electrokinetic Phenomena
 Review Questions
 References
 Problems

13. Electrostatic and PolymerInduced Colloid Stability
 13.1 Introduction
 13.2 Interparticle Forces and the Structure and Stability of Dispersions
 13.3 The DerjaguinLandauVerweyOverbeek Theory of Colloid Stability
 13.4 Theory of Coagulation in Dilute Dispersions
 13.5 PolymerColloid Mixtures: A Phenomenological Perspective
 13.6 PolymerInduced Forces
 13.7 Steric Stabilization: A Model for the Initial Encounter
 Review Questions
 References
 Problems
 Appendix A: Examples of Expansions Encountered in This Book
 Appendix B: Units: CGSSI Interconversions
 Appendix C: Statistics of Discrete and Continuous Distributions of Data
 Appendix D: List of WorkedOut Examples
 Index
Product information
 Title: Principles of Colloid and Surface Chemistry, Revised and Expanded, 3rd Edition
 Author(s):
 Release date: October 2016
 Publisher(s): CRC Press
 ISBN: 9781351990738
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