October 2004
Intermediate to advanced
527 pages
13h 50m
English
Content preview from Advanced Organic ChemistryBecome an O’Reilly member and get unlimited access to this title plus top books and audiobooks from O’Reilly and nearly 200 top publishers, thousands of courses curated by job role, 150+ live events each month,
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6
Free Radical Reactions
LEARNING OBJECTIVES
By the end of this chapter you should be familiar with
- Evidence for the existence of radicals, their detection and characterization.
- Structure and bonding of radicals. Radical reactions follow different rules to those of ionic reactions.
- Generation, stability and reactions of free-radicals. Radicals favour conjugate addition.
- Stereochemistry of radical substitution reactions.
- Cyclization is easy with radical reactions.
6.1 INTRODUCTION
A carbon-centered radical is a structure having an unpaired electron on a carbon atom and a formal charge of zero. Thus, a free radical is an atom or a group of atoms with an unpaired electron. (This definition includes certain stable, inorganic molecules and atoms ...
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I'm always learning. So when I got on to O'Reilly, I was like a kid in a candy store. There are playlists. There are answers. There's on-demand training. It's worth its weight in gold, in terms of what it allows me to do.