October 2004
Intermediate to advanced
527 pages
13h 50m
English
Content preview from Advanced Organic ChemistryBecome an O’Reilly member and get unlimited access to this title plus top books and audiobooks from O’Reilly and nearly 200 top publishers, thousands of courses curated by job role, 150+ live events each month,
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9
Stereochemistry
LEARNING OBJECTIVES
By the end of this chapter you should be familiar with
- Representation of three dimensional molecules in two dimensions.
- The hybridization of carbon in alkanes, alkenes and alkynes.
- Chair and boat conformations, ring inversion and 1,3-diaxial interactions in cyclohexanes.
- Chirality, Fischer, Newman and saw-horse projections, R/S, erythro/threo and syn/anti configuration, meso configuration, enantiomers and diastereoisomers, racemization and resolution.
9.1 INTRODUCTION
Vladimir Prelog performed wide-ranging research on the stereochemistry of alkaloids, antibiotics, enzymes and other natural compounds. In particular, he contributed to the understanding of stereoisomerism, in which two compounds of identical ...
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