Appendix FHeat Capacity Equations

Table F.1 Heat Capacity Equations for Organic and Inorganic Compounds (at Low Pressures)*

Forms:

(1)Cpo=a+b(T)+c(T)2+d(T)3;(2)Cpo=a+b(T)+c(T)2.

Units of Cpo are J/(g mol)(K or °C).

To convert to cal/(g mol)(K or °C) = Btu/(lb mol)(°R or °F), multiply by 0.2390.

Note: b · 102 means the value of b is to be multiplied by 10–2, e.g., 20.10 × 10–2 for acetone.

Compound

Formula

Mol. Wt.

State

Form

T

a

b · 102

c · 105

d · 109

Temp. (in T)

Acetone

CH3COCH3

58.08

g

1

°C

71.96

20.10

−12.78

34.76

0−1200

Acetylene

C2H2

26.04

g

1

°C

42.43

6.053

−5.033

18.20

0−1200

Air

29.0

g

1

°C

28.94

0.4147

0.3191

−1.965

0−1500

g

1

K

28.09

0.1965

0.4799

−1.965

273−1800

Ammonia

NH3

17.03

g

1

°C

35.15

2.954 ...

Get Basic Principles and Calculations in Chemical Engineering, 9th Edition now with the O’Reilly learning platform.

O’Reilly members experience books, live events, courses curated by job role, and more from O’Reilly and nearly 200 top publishers.