January 2016
Intermediate to advanced
448 pages
13h 46m
English
Content preview from Handbook of Single-Molecule Electronics
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July 1, 2015 11:4 PSP Book - 9in x 6in 07-Kasper-Moth-Poulsen-c07
220 Self-Assembly at Interfaces
Figure 7.16 Adsorption sites on Au(111) surface. Top and side views show
hollow site, bridge site, and on-top site adsorption.
The detailed surface geometry is typically more complicated.
Some proposed structures of adsorption sites are disulfide bonding
(Fig. 7.17a), a complex that involves an Au adatom binding to
the thiolate (Fig. 7.17b), and a polymeric chain structure with
monothiolates bridging Au adatoms (Fig. 7.17c).
Jones et al. [39, 40] indicate Au top-site adsorptions of thiolates,
which would prove that there are mobile Au–SR complexes on the
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