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Thermodynamics, 5th Edition

Name: Thermodynamics, 5th Edition
Author: Jurgen M. Honig
ISBN: 9780128233696

by Jurgen M. Honig

November 2020

Intermediate to advanced

492 pages

15h 54m

English

Academic Press

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Cover image
Title page
Table of Contents
Copyright
General Commentary
Preface
Chapter 1. Fundamentals
1.1 Introductory DefinitionsRemarks and Queries1.2 The Zeroth Law of ThermodynamicsAdditional Information1.3 Mathematical ApparatusRemarks1.4 Thermodynamic ForcesReference1.5 Elements of WorkSummary
Comment and Queries
1.6 The Element of Work for a System Subjected to Electromagnetic FieldsRemark and Reference1.7 The First Law of ThermodynamicsReferenceNotes1.8 The Second Law of ThermodynamicsFootnotes and Query1.9 Consequences of the First and Second LawsSummaryRemarks and Questions1.10 Functions of State; Reprise
Summary
Appendix A Remarks Concerning Irreversible ProcessesAppendix B Time-Dependent Irreversible ProcessesReferenceNotes
1.11 Statements of the Second Law; Thermodynamic Operation of Heat Engines; Kelvin and Planck Statements; Temperature Scale
Exercise1.12 Systematization of Results Based on Functions of State

Review of Electronic Properties of Metals
Exercises and Remark1.13 The Third Law of ThermodynamicsRemarks and Queries1.14 The Gibbs–Duhem Relation and Its AnalogsQuery and Reference1.15 Heat Capacities; Fundamentals and Applications
Acknowledgment
Exercises and Comments1.16 Effect of Chemical Changes on the Energy of a System1Remarks1.17 Stability of a System; FluctuationsAppendicesReference
Chapter 2. Thermodynamic Properties of Ideal Systems
2.1 Equilibrium in a System of Several Components and Phases2.2 Achievement of EquilibriumComment and Exercise2.3 System of One Component and Several Phases; the Clausius– Clapeyron EquationReference and Footnote2.4 Properties of Ideal GasesExercises2.5 Properties of Ideal Solutions in Condensed Phases
Reference
2.6 The Duhem–Margules Equation and Its Consequences2.7 Temperature Dependence of Composition of Solutions2.8 Lowering of the Freezing Point and Elevation of the Boiling Point of a SolutionExercise2.9 General Description of Chemical Reactions and Chemical Equilibrium; Application to GasesRemarks2.10 Chemical Equilibrium in Homogeneous Condensed Ideal SolutionsComments2.11 Chemical Equilibrium in Ideal Heterogeneous Systems2.12 Equilibrium between Two Ideal Phases
Chapter 3. Characterization of Nonideal Solutions
3.0 Introductory Remarks3.1 Thermodynamic Treatment of Nonideal Gas MixturesNotes and Exercise3.2 Temperature and Pressure Dependence of the Fugacity of a Gas3.3 Thermodynamic Description of Real Solutions in the Condensed StateQuery and Reference3.4 Characterization of Chemical Equilibrium in Nonideal Solutions3.5 Pressure and Temperature Dependence of Activities and Activity Coefficients3.6 Determination of Activity Coefficients and Calorimetric Quantities in Chemical Processes
References and Commentary
3.7 Determination of Activities from Freezing Point Lowering of Solutions3.8 Thermodynamic Properties of Nonideal Solutions
Exercises
Exercises
3.9 Dependence of Higher Order Phase Transitions on TemperatureExercises and References3.10 Elements of Order–Disorder Theory and ApplicationsReferences
Chapter 4. Thermodynamic Properties of Electrolytes and of EMF Cells
4.0 Introductory Comments4.1 Activities of Strong ElectrolytesExercise and Comment4.2 Theoretical Determination of Activities in Electrolyte Solutions; the Debye–Hückel EquationComment and ExercisesExperimental Determination of Activities and Activity Coefficients of Strong ElectrolytesEquilibrium Properties of Weak Electrolytes
Exercise
4.3 Galvanic CellsRemarks4.4 Operation of Galvanic CellsRemarks4.5 Galvanic Cells; Operational Analysis4.6 Liquid Junction Potentials4.7 EMF Dependence on ActivitiesExamples of Operating CellsTypes of Operating CellsQueries4.8 Thermodynamic Information from Galvanic CellsAssignment
Chapter 5. Thermodynamic Properties of Materials in Externally Applied Fields
5.0 Introductory Comments5.1 Thermodynamics of Gravitational and Centrifugal FieldsComment and Exercises5.2 Thermodynamics of Adsorption ProcessesReferences and Exercises5.3 Heats of Adsorption
Summary
Reference and Exercises5.4 Surface vs Bulk Effects: Thermodynamics of Self-AssemblyReferences5.5 Pressure of Electromagnetic Radiation5.6 Thermodynamic Characterization of Electrodynamic Radiation
Exercises
5.7 Effects of Electric Fields on Thermodynamic Properties of MatterReference and Exercises5.8 Systematization of Electromagnetic Field Effects in ThermodynamicsComments and Assignments5.9 Adiabatic Diamagnetization and Transitions to Superconductivity
5.10 Thermodynamic Characterization of Anisotropic Media
Reference5.11 Thermodynamic Properties of Anisotropic MediaReference and Exercise5.12 Thermodynamics of Interacting Electron AssembliesRemarks and References
Chapter 6. Irreversible Thermodynamics
6.0 Introductory Comments6.1 GeneralitiesNotes and Queries6.2 Shock PhenomenaExercises6.3 Linear Phenomenological Equations6.4 Steady-State Conditions and Prigogine's TheoremComments and Questions6.5 Onsager Reciprocity ConditionsReference6.6 Thermomolecular Mechanical Effects
6.7 Electrokinetic Phenomena
Exercises6.8 The Soret EffectExercises6.9 Thermoelectric EffectsComments and Exercises6.10 Irreversible Thermomagnetic Phenomena in Two DimensionsExercises
Chapter 7. Critical Phenomena
7.0 Introductory Remarks7.1 Properties of Materials Near Their Critical PointNotes and References7.2 Homogeneity Requirements, Correlation Lengths, and Scaling PropertiesFootnotes7.3 Derivation of Griffith’s and Rushbrooke’s Inequality
Reference and Exercise
7.4 Scaled Equation of StateReference7.5 Landau Theory of Critical Phenomena and Phase TransitionsReferenceReference
Chapter 8. Topics Related to Critical Phenomena
8.1 Homogeneous Functions8.2 Fixed Points8.3 Remarks Concerning Chaos Theory8.4 Appendix: The Role of Fisher Information Theory in the Development of Physical Laws8.5 References
Chapter 9. Reprise to the Second Law. Mathematical Proof of the Carathéodory Theorem and Resulting Interpretations
9.1 Fundamentals9.2 Proof of Holonomicity9.3 Necessary Condition for Establishing the Carathéodory's Theorem9.4 Relevance to Thermodynamics9.5 Derivation of the Limiting Form for the Debye–H}uckel EquationReferences and Query
Chapter 10. Elements of Statistical Thermodynamics
10.1 Distributions and Statistics10.2 The Boltzmann Relation for the Entropy10.3 Distribution Functions10.4 Digression on the Concepts of Work and Heat10.5 Statistical Representation of Functions of State10.6 Summary10.7 Alternative Statistical Interpretation for Entropy in Terms of Properties of a SystemFootnotes10.8 Derivation of Curie’s Law and Ohm’s Law
Index

Content preview from Thermodynamics, 5th Edition

(7.3.9c)

To satisfy the inequality (7.3.8), the two integrals on the right must be so formulated that the integrands remain positive. These two integrals then are required to have a form that may be evaluated by standard methods to yield

$I_{1} = (D / (V_{g} - V_{c})) \int_{V_{c}}^{V_{g}} {(V - V_{c})}^{δ} d V = D {(V_{g} - V_{c})}^{δ} / (1 + δ)$ (7.3.10a)

(7.3.10a)

and

$I_{2} = (D / (V_{c} - V_{l})) \int_{V_{l}}^{V_{c}} {(V_{c} - V)}^{δ} d V = D {(V_{c} - V_{l})}^{δ} / (1 + δ) .$ (7.3.10b)

(7.3.10b)

Then,

$I_{1} + I_{2} = \frac{D}{1 + δ} [{(V_{g} - V_{c})}^{δ} + {(V_{c} - V_{l})}^{δ}] = \frac{2 D B^{δ} T_{c}^{β δ}}{1 + δ} {(1 - \frac{T}{T_{c}})}^{β δ} .$ (7.3.11)

(7.3.11) ...

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Thermodynamics, 5th Edition

by Jurgen M. Honig

Become an O’Reilly member and get unlimited access to this title plus top books and audiobooks from O’Reilly and nearly 200 top publishers, thousands of courses curated by job role, 150+ live events each month,
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