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Fundamentals of Chemical Engineering Thermodynamics

by Themis Matsoukas

October 2012

Intermediate to advanced

720 pages

18h 17m

English

Pearson

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1.1 Molecular Basis of Thermodynamics1.2 Statistical versus Classical Thermodynamics1.3 Definitions1.4 Units1.5 Summary1.6 Problems
2.1 The PVT Behavior of Pure Fluid2.2 Tabulation of Properties2.3 Compressibility Factor and the ZP Graph2.4 Corresponding States2.5 Virial Equation2.6 Cubic Equations of State2.7 PVT Behavior of Cubic Equations of State2.8 Working with Cubic Equations2.9 Other Equations of State2.10 Thermal Expansion and Isothermal Compression2.11 Empirical Equations for Density2.12 Summary2.13 Problems
3.1 Energy and Mechanical Work3.2 Shaft Work and PV Work3.3 Internal Energy and Heat3.4 First Law for a Closed System3.5 Elementary Paths3.6 Sensible Heat—Heat Capacities3.7 Heat of Vaporization3.8 Ideal-Gas State3.9 Energy Balances and Irreversible Processes3.10 Summary3.11 Problems
4.1 The Second Law in a Closed System4.2 Calculation of Entropy4.3 Energy Balances Using Entropy4.4 Entropy Generation4.5 Carnot Cycle4.6 Alternative Statements of the Second Law4.7 Ideal and Lost Work4.8 Ambient Surroundings as a Default Bath—Exergy4.9 Equilibrium and Stability4.10 Molecular View of Entropy4.11 Summary4.12 Problems
5.1 Calculus of Thermodynamics5.2 Integration of Differentials5.3 Fundamental Relationships5.4 Equations for Enthalpy and Entropy5.5 Ideal-Gas State5.6 Incompressible Phases5.7 Residual Properties5.8 Pressure-Explicit Relations5.9 Application to Cubic Equations5.10 Generalized Correlations5.11 Reference States5.12 Thermodynamic Charts5.13 Summary5.14 Problems
6.1 Flow Streams6.2 Mass Balance6.3 Energy Balance in Open System6.4 Entropy Balance6.5 Ideal and Lost Work6.6 Thermodynamics of Steady-State Processes6.7 Power Generation6.8 Refrigeration6.9 Liquefaction6.10 Unsteady-State Balances6.11 Summary6.12 Problems
7.1 Two-Phase Systems7.2 Vapor-Liquid Equilibrium7.3 Fugacity7.4 Calculation of Fugacity7.5 Saturation Pressure from Equations of State7.6 Phase Diagrams from Equations of State7.7 Summary7.8 Problems
8.1 The Txy Graph8.2 The Pxy Graph8.3 Azeotropes8.4 The xy Graph8.5 VLE at Elevated Pressures and Temperatures8.6 Partially Miscible Liquids8.7 Ternary Systems8.8 Summary8.9 Problems
9.1 Composition9.2 Mathematical Treatment of Mixtures9.3 Properties of Mixing9.4 Mixing and Separation9.5 Mixtures in the Ideal-Gas State9.6 Equations of State for Mixtures9.7 Mixture Properties from Equations of State9.8 Summary9.9 Problems
10.1 Gibbs Free Energy of Mixture10.2 Chemical Potential10.3 Fugacity in a Mixture10.4 Fugacity from Equations of State10.5 VLE of Mixture Using Equations of State10.6 Summary10.7 Problems
11.1 Ideality in Solution11.2 Fugacity in Ideal Solution11.3 VLE in Ideal Solution–Raoult’s Law11.4 Energy Balances11.5 Noncondensable Gases11.6 Summary11.7 Problems
12.1 Excess Properties12.2 Heat Effects of Mixing12.3 Activity Coefficient12.4 Activity Coefficient and Phase Equilibrium12.5 Data Reduction: Fitting Experimental Activity Coefficients12.6 Models for the Activity Coefficient12.7 Summary12.8 Problems
13.1 Equilibrium between Partially Miscible Liquids13.2 Gibbs Free Energy and Phase Splitting13.3 Liquid Miscibility and Temperature13.4 Completely Immiscible Liquids13.5 Solubility of Gases in Liquids13.6 Solubility of Solids in Liquids13.7 Osmotic Equilibrium13.8 Summary13.9 Problems
14.1 Stoichiometry14.2 Standard Enthalpy of Reaction14.3 Energy Balances in Reacting Systems14.4 Activity14.5 Equilibrium Constant14.6 Composition at Equilibrium14.7 Reaction and Phase Equilibrium14.8 Reaction Equilibrium Involving Solids14.9 Multiple Reactions14.10 Summary14.11 Problems

Content preview from Fundamentals of Chemical Engineering Thermodynamics

Appendix D. UNIFAC Tables

Table D-1: Parameters for the UNIFAC Equation. “Main” refers to the index of the main group; k refers to the index of the subgroup.

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