October 2012
Intermediate to advanced
720 pages
18h 17m
English
Content preview from Fundamentals of Chemical Engineering ThermodynamicsBecome an O’Reilly member and get unlimited access to this title plus top books and audiobooks from O’Reilly and nearly 200 top publishers, thousands of courses curated by job role, 150+ live events each month,
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Chapter 4. Entropy and the Second Law
The first law, discussed in the previous chapter, expresses a fundamental principle, energy conservation. All processes observed in nature are bound to satisfy this principle. To put this differently, a process is physically impossible if it violates the first law. The opposite, however, is not true: not every process that satisfies the first law is in fact possible. Consider this familiar situation: if we throw a piece of ice in warm water and leave the system undisturbed, the ice will melt and the water will become colder. This process satisfies the first law, as the amount of energy that is absorbed by the ice is equal to the energy (heat) rejected by the warm water. Now, consider the same process in reverse: ...
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