Fundamentals of Chemical Engineering Thermodynamics

Index

Note: page numbers with “f” indicate figures; those with “t” indicate tables.

Absolute temperature, 23–24

Absolute zero, 22t

Accumulation, 253

Acentric factor, 47–51

defined, 47–48

of simple, normal, and polar fluids, 50–51

Activity, 606–13

chemical potential and, 607

of gas, 607–8, 611

of liquid, 608–9, 611

P°, working with, 608

of solid, 609–10, 612

of solute, 609, 611–12

standard state and, 610, 613

Activity coefficient, 504–11

for data reduction, 512–15

defined, 504

deviations from Raoult’s law, 508–10, 509f

experimental, 510–15

Gibbs free energy and, excess, 505–7, 510–14, 511f

limits of, 505

phase equilibrium and, 507–10

solubility limits using, 547–48

usefulness of, 505

Activity coefficient models, 515–31

Flory-Huggins, 521–22