March 2013
Intermediate to advanced
406 pages
14h 48m
English
Content preview from Perturbation Theories for the Thermodynamic Properties of Fluids and Solids
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Inhomogeneous Systems 331
Equation 8.151. The theory was used to predict the surface tension of the LJ fluid, in
excellent agreement with the simulations, and to correlate the experimental data on
the liquid–vapor equilibrium and the surface tension of several alkane and aromatic
compounds.
Another approximation was derived by Tripathi and Chapman (2005a,b) for
homonuclear chains within the framework of the SAFT and was denoted inhomo-
geneous/interfacial SAFT (i-SAFT). The theory, in which the HS contribution is
approximated by the Rosenfeld FMT and the attractive contribution is again treated
in the MF approximation, reduces to the SAFT for the bulk fluid. It was used by
Tripathi and Chapman (2005a,b) to predict the segment density profiles and
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