February 2014
Intermediate to advanced
416 pages
15h 55m
English
Content preview from Encyclopedic Dictionary of Named Processes in Chemical Technology, 4th Edition
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351
T
Trail
Toth Also called TAC [Toth Aluminum Corporation] A method proposed for making aluminum metal from
clay. The dried clay, mixed with coke, is chlorinated to yield aluminum trichloride and silicon tetrachlo-
ride. The volatile chlorides are separated by distillation, and the aluminum chloride is then reduced with
manganese metal:
Al Si Oxy/ Cl z CxAlCl ySiCl z CO
xyz
++ += ++() //3422 2
23
42
2323
32
AlCl Mn Al MnCl+=+
The manganese chloride is then reduced with hydrogen:
MnCl H Mn HCl
22
2+= +
and the manganese metal reused. In another version, the manganese chloride is oxidized in oxygen to manga-
nese oxide, which is then re ...
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