October 2013
Intermediate to advanced
242 pages
9h 22m
English
Content preview from Methods of Non-a-Amino Acid Synthesis, 2nd Edition
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Methods of Non-α-Amino Acid Synthesis, Second Edition
3.2 CARBON NUCLEOPHILES
3.2.1 nitRo enolates and nitRile enolates
Certain amine surrogates can add to conjugated carbonyl systems if that surrogate
can be converted to a carbanionic species, typically an enolate anion. Addition
of these species to conjugated acid derivatives will give an amino acid, but a sec-
ond reaction is required to convert the surrogate to the amino group. This section
will describe reactions of specialized enolate anions that participate in Michael
additions,
26
but it is noted that Chapter 4 is devoted to enolate anion reactions of all
types that will produce an a ...
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