September 2006
Intermediate to advanced
680 pages
22h 22m
English
book
Ultrashort Laser Pulse Phenomena, 2nd Edition
by Jean-Claude Professor Diels, Jean-Claude Diels, Wolfgang Rudolph
Content preview from Ultrashort Laser Pulse Phenomena, 2nd Edition
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Primary Steps in Photo–Biological Reactions 551
Isomerization coordinate
200 fs
460 540500
Wavelength (nm)
33 fs
400 fs
6 ps
3
2
1
0
1
2
c
580
a
200 fs
h$
h$
Energy (kcal/mole)
b
S
0
S
1
S
n
100
50
0
11-cis rhodopsin
CH
3
CH
3
CH
3
CH
3
11
11
12
12
NH
N
H
All-trans photoproduct
Figure 11.12 Schematic representation of the photo-isomerization reaction of rhodopsin.
(a) Ground and excited state potential energy curves as a function of the torsional coordinate. The
spectrum is red-shifted after absorption of a photon at 500 nm. The classical sketch of the cis-trans
transformation is shown in (b). (c) Difference spectra measurements of 11-cis-rhodopsin at various
delays following a 35-fs pump
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