January 2015
Intermediate to advanced
412 pages
12h 10m
English
Content preview from Electrochemical Biosensors
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November 11, 2014 15:52 PSP Book - 9in x 6in 11-Serge-Cosnier-c11
QD Electrodes for Detection of Small Molecules in Solution 319
11.4 QD Electrodes for Detection of Small Molecules in
Solution
When the scheme in Fig. 11.2 is correct, then it should be possible
to detect different concentrations of redox-active substances in
solution by choosing a proper potential and illumination of the
electrode surface. This has been shown with the simple ferri-
/ferrocyanide system. In these cases an enhanced photocurrent
is detected. For example, a light-induced reduction current is
found for a CdSe/ZnS electrode at −250 mV versus Ag/AgCl when
hexacyanoferrate (III) ...
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