September 2014
Intermediate to advanced
576 pages
19h 57m
English
Content preview from Emerging Nanotechnologies for Manufacturing, 2nd Edition
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20 CHAPTER 2 Gas phase nanofication
FIGURE 2.1
(a) Temperature dependence of the equilibrium oxygen partial pressure in: 1, Mo/MoO
3
; 2,
W/WO
3
; 3, Mo/MoO
2
; 4, W/WO
2
; 5, Zn/ZnO; 6, Ti/TiO
2
and 7, Ti/TiO; (b) Mo/MoO
3
; (c) W/
WO
3
and (d): Ti/TiO
2
and Ti/TiO systems. The variation in
p
O
2
by changing the CO
2
/CO ratio
between 10
−5
and 10
5
at 450°C, 600°C and 800°C is also shown (open triangles).
0
−10
−20
−40
−30
623 723 823 923 1023 1123
T(K)
10
5
10
2
10
-2
4
Sysmbol
−5
−15
−25
−35
623 723823 923 1023 1123
T(K)
10
5
10
2
10
-2
4
Sysmbol
−5
−15
−25
−35
−45
−55
−65
−75
623 673723 773823 873923 973 1023 1073 1123
log
10
Po
2
(atm)
log
10
Po
2
(atm) log
10
Po
2
(atm)
log
10
Po
2
(atm)
T(K)
−5
−15
−25
−35 ...
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