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10
Silicon Wafer Preparation for
VLSI and ULSI Processing
10.1 Introduction
Metallic contamination in silicon wafers has harmful effects on device performance and
circuits fabricated with them. It is well established that minor amounts of metals can degrade
thin oxide lm quality, leakage current densities, and minority carrier lifetimes. Fast-diffusing
metal impurities, such as copper, nickel, and palladium, easily precipitate at the wafer sur-
faces, causing small structural defects called S-pits, or, in a higher density, resulting in haze [1].
The formation of the S-pits and surface haze has been correlated with the generation of
oxidation- ...