Appendix 8: Important Relationships

CONTENTS

 

A8.1 DEFINITION OF TERMS FOR ATTACHMENT

As an example we consider the molecule chloromethane (CH3Cl). The potential curve of the molecule and its negative ion are drawn to scale as shown in Figure A8.1 (Barszczewska et al., 2003). The following quantities are easy to identify (see Table A8.1).

A negative sign is usually assigned to the electron affinity (EA) of the molecule, if the asymptote of the negative ion curve ...

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