July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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7 Anionic Polymerization
Anionic polymerization is a type of chain growth polymerization that involves the polymerization of monomers initiated with anions. In 1936, Karl Ziegler reported the first anionic polymerization of styrene and butadiene by consecutive addition of monomer to an alkyl lithium initiator, which occurred without chain transfer or termination. Twenty years later, living polymerization was demonstrated by Szwarc and coworkers.
The monomers that are susceptible to anionic polymerization are those that can form stable carbanionic species under polymerization conditions. The most studied monomers are styrenic, dienic, and cyclic and can react with nucleophiles, leading to ring opening.
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