July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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193 Ring-Opening Polymerization
Ring-opening polymerization (ROP) is a form of chain-growth polymerization in which the terminal end-group of a polymer chain acts as a reactive center where further cyclic monomers can react by ring-opening and addition of the broken bond to form a longer polymer chain. The reactive center can be radical, anionic, or cationic. Some cyclic monomers such as norbornene or cyclooctadiene can be polymerized to high-molecular-weight polymers by using metal catalysts.
ROP has been used since the beginning of the 1900s, and the mechanisms and thermodynamics of ROP were established in the 1950s. The first high-molecular-weight polymers (Mn up to 105) with a repeating unit were prepared ...
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