July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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212 Step-Growth Polymerization
Step-growth polymerization refers to a type of polymerization mechanism in which bifunctional or multifunctional monomers react to form first dimers, then trimers, longer oligomers, and eventually long-chain polymers (Figure 212.1).
IUPAC has deprecated the term step-growth polymerization and recommends use of the terms polyaddition, when the propagation steps are addition reactions and no molecules are evolved during these steps, and polycondensation, when the propagation steps are condensation reactions and molecules are evolved during these steps.
The first synthetic polymeric material, Bakelite, was announced by Leo Baekeland in 1907, through a typical step-growth polymerization ...
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