July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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223 Telomerization
Telomerization refers to a chemical reaction involving the addition of fragments of one molecule, which is called a telogen such as an alcohol, acetal, or chloroform, to the ends of a polymerizing olefin molecule (called a taxogen). The products of this reaction are called telomers.
Telomerization can be initiated by radical anionic or cationic systems.
Applications:
Telomerization provide a synthesis method of a wide range of possible products. Two telomerization reactions are currently performed on an industrial scale. The first one is the Kuraray process, which is based on the telomerization of butadiene with water, also called hydrodimerization, forming 1-octanol. The process was implemented ...
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