July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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34 Condensation Polymerization
Condensation polymerization is a form of step-growth polymerization in which monomers and/or oligomers react with each other to form larger structural units while releasing smaller molecules as a byproduct such as water or methanol.
Important condensation reactions are esterification, ester interchange, etherification, and amidization. A classic step-growth condensation is the reaction between a dibasic acid and a glycol, shown here:
HOOC–(CH2)n–COOH + HO–(CH2)m–OH→
HOOC–(CH2)n–COO–(CH2)m–OH + H2O
Applications:
One important class of condensation polymers are polyamides. Nylon is a typical example, which was the first commercially successful synthetic thermoplastic polymer. Nylon ...
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