July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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176 Polyphosphazenes
Polyphosphazenes (PPHOSs) are polymers with an inorganic backbone consisting of alternating phosphorus and nitrogen atoms, separated by alternating single and double bonds, and organic substituents (R) covalently bonded to the phosphorus atoms as side groups.
PPHOSs were reported as early as the 1890s. A breakthrough happened in the 1960s with soluble poly(dichloro)phosphazene, which was the precursor of PPHOSs, that was first achieved by H. R. Allcock and coworkers. It was found that through nucleophilic attack, the chlorine atoms of poly(dichloro)phosphazene can be readily replaced by organic nucleophiles to give stable PPHOSs, which can be processed and formed into materials with a wide ...
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