July 2024
Intermediate to advanced
280 pages
12h 52m
English
Content preview from The Essential Handbook of Polymer Terms and Attributes
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120 Optically Healable Polymers
Optically healable/photo-healable polymers are a type of stimuli-responsive, self-healing polymer that harness the external visible or ultraviolet (UV) light to activate the self-healing reaction around the fracture interface.
There are several optically healable mechanisms based on the structure/composition of the polymers. The self-healing can be achieved through reversible dynamic covalent bonds, metal-ligand coordination, photoisomerization, and non-covalent bonds.
For example, when a metallosupramolecular polymer is exposed to UV light, the metal-ligand motifs are electronically excited and the absorbed energy is converted into heat. This causes temporary disengagement of ...
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